چكيده به لاتين
In this project, the synthesis of some of these metal-organic frameworks has been done using the green ball milling method. The metal sources used in synthesis and post-synthesis modification of these structures include copper, cobalt, nickel and palladium metal salts. Also, terephthalic acid, 2-amino terephthalic acid, 1,4-diazabicyclo[2.2.2]octane (DABCO) and benzene-1,3,5-tricarboxylic acid were used to synthesize these structures. Then, the catalytic properties of the synthesized frameworks, in condensation reactions such as Knoevenagel, the preparation of 1-amidoalkyl-2-naphthol derivatives, oxidative reaction of benzyl alcohols, oxidative coupling to prepare enol and phenolic carbamates, and Suzuki coupling has been investigated. Not using solvent in the preparation of frameworks, short time, green methods, high yields in reactions, catalyst easy separation, catalyst reuse and no significant reduction in catalyst activity after several recovery steps are the benefits of the present project.
